ISSN

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online 2570-7345

Neobvyklá asociace minerálů s willemitem z prostoru centrální části příbramského uran - polymetalického revíru (Česká republika)

Unusual mineralization with willemite from the area of the central part of the Příbram uranium and base-metal district (Czech Republic)


DOI: https://doi.org/10.46861/bmp.30.224

Klíčová slova

Abstrakt

The unusual mineralization with willemite, rare Cu arsenides (koutekite, kutinaite) and balkanite was found at a sample originating from the Jerusalém deposit (shaft No. 9), Příbram uranium and base-metal ore district (Czech Republic). The gangue is formed by earlier siderite and quartz intensively replaced by abundant willemite and younger dolomite group minerals with hematite inclusions and the youngest calcite. The ore mineralization represented by sphalerite, djurleite, anilite, covellite, stromeyerite, balkanite, koutekite, kutinaite, primary anglesite and Hg-rich silver is accompanied by Zn-rich hisingerite, baileychlore and Fe-oxides with variable but significant Si contents. The detailed description and quantitative chemical data for individual mineral phases are given. The studied mineralization was formed in significantly changing redox conditions (from reducing to highly oxidizing) with a distinct decrease of temperature (down to below 70(3) °C).

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Reference

Anthony JW, Bideaux RA, Bladh KW, Nichols MC (1990) Handbook of mineralogy. Volume I Elements, sulfides, sulfosalts. 588 s., Mineral Data Publishing Tuscon. https://doi.org/10.1180/minmag.1991.055.378.20

Atanassov VA, Kirov GN (1973) Balkanite, Cu9Ag5HgS8, a new mineral from the Sedmochislenitsi mine, Bulgaria. Am Mineral 58: 11-15

Belendorff K (1986) A paragenesis of rare minerals from Nieder-Beerbach, Odenwald, Germany: Lautite, kutinaite, paxite. N Jb Mineral, Mh 11: 511-518

Berner RA (1969) Goethite stability and the origin of red beds. Geochim Cosmochim Acta 33: 267-273. https://doi.org/10.1016/0016-7037(69)90143-4

Biagioni C, Bindi L (2017) Ordered distribution of Cu and Ag in the crystal structure of balkanite, Cu9Ag5HgS8. Eur J Mineral 29: 279-285. https://doi.org/10.1127/ejm/2017/0029-2591

Bindi L, Makovicky E (2015) Crystal structure and chemistry of natural kutinaite from Černý Důl, Krkonoše, Czech Republic. Mineral Mag 79: 1099-1109. https://doi.org/10.1180/minmag.2015.079.5.06

Bobos I, Jaques L, Noronha F, Clauer N, Liewig N (2005) Geochemistry, geothermometry, and K-Ar dating of episyenitic rocks associated with the Guarda uraniferous granites, Portugal. In: Mao J, Bierlein FP (eds.): Mineral deposit research: meeting the global challenge, Session 3: 225-228. Springer Verlag, Berlin etc. https://doi.org/10.1007/3-540-27946-6_58

Brugger J, McPhail DC, Wallace M, Waters J (2003) Formation of willemite in hydrothermal environments. Econ Geol 98: 819-835. https://doi.org/10.2113/gsecongeo.98.4.819

Cílek V, Prokeš S, Škubal M, Hladíková J, Šmejkal V, Žák K (1984) Geochemie hydrotermálních karbonátů příbramského uranového ložiska. Vlast sbor Podbrdsk 26: 79-102

Dolníček Z, Krejčí Kotlánová M (2022) Hluboká diagenetická alterace těžkých minerálů v pískovcích z lokality Lukoveček (račanská jednotka, flyšové pásmo Vnějších Západních Karpat, Česká republika). Acta Mus Moraviae, Sci geol 107: 53-71

Dolníček Z, René M, Hermannová S, Prochaska W (2014) Origin of the Okrouhlá Radouň episyenite-hosted uranium deposit, Bohemian Massif, Czech Republic: fluid inclusion and stable isotope constraints. Mineral Deposita 49(4): 409-425. https://doi.org/10.1007/s00126-013-0500-5

Dolníček Z, Ulmanová J, Sejkora J., Knížek F, Škácha P (subm.) Mineralogy and genesis of the Pb-Zn-Sb-Ag vein H32A in the Příbram uranium and base-metal district, Bohemian Massif, Czech Republic. Ore Geol Rev submitted

Eggleton RA, Tilley DB (1998) Hisingerite: A ferric kaolin mineral with curved morphology. Clays Clay Miner 46: 400-413. https://doi.org/10.1346/ccmn.1998.0460404

Ettler V, Sejkora J, Drahota P, Litochleb J, Pauliš P, Zeman J, Novák M, Pašava J (2010) Příbram and Kutná Hora mining districts - from historical mining to recent environmental impact. Acta Miner - Petr, Field Guide Series 7: 1-23

Fiala V, Čadek J (1981) Hydrotermální alterace na ložisku Okrouhlá Radouň. Sborn Geol Věd, Lož Geol Mineral 22: 159-199

Gablina IF, Mozgova NN, Borodaev YS, Stepanova TV, Cherkashev GA, Il´in MI (2000) Copper sulfide association in recent oceanic ores of the Logachev hydrothermal field (Mid-Atlantic Ridge, 14 degrees 45´ N). Geol Ore Depos 42: 296-316

Garrett DE (1992) Natural soda ash: Occurrences, processing and use. Van Nostrand Reinhold, New York

Garrett DE (2001) Sodium sulfate: Handbook of deposits, processing, properties, and use. Academic Press, San Diego, etc.

Goble RJ (1980) Copper sulfides from Alberta: yarrowite Cu9S8 and spionkopite Cu39S28. Can Mineral 18: 511-518

Goble RJ (1981) The leaching of copper from anilite and the production of metastable copper sulfide structure. Can Mineral 19: 583-592

Goble RJ, Robinson G (1980) Geerite, Cu1.60S, a new copper sulfide from Dekalb township, New York. Can Mineral 18, 519-523

Grønvold F, Westrum EF (1980) The anilite/low digenite transition. Am Mineral 65: 574-575

Hak J, Johan Z, Skinner BJ (1970) Kutinaite; a new copper-silver arsenide mineral from Černý Důl, Czechoslovakia. Am Mineral 55: 1083-1087

Hanuš V (1956) Mineralogie a geochemie Cu-Pb-Zn žíly s chalkosinem a willemitem u Vrančic na Příbramsku. Sbor Ústř Úst geol 22: 69-143

Harris DC, Thorpe RI (1985) Occurrence of copper arsenides in the East Arm area, Great Slave Lake, District of Mackenzie. Geol Survey of Can 85-1A: 713-716. https://doi.org/10.4095/120180

Hatert F (2005) Transformation sequences of copper sulfides at Vielsalm, Stavelot Massif, Belgium. Can Mineral 43: 623-635. https://doi.org/10.2113/gscanmin.43.2.623

Charoy B, Pollard PJ (1989) Albite-rich, silica-depleted metasomatic rocks at Emuford, Northeast Queensland; mineralogical, geochemical, and fluid inclusion constraints on hydrothermal evolution and tin mineralization. Econ Geol 84: 1850-1874 . https://doi.org/10.2113/gsecongeo.84.7.1850

Johan Z (1958) Koutekite: a new mineral. Nature 181: 1553. https://doi.org/10.1038/1811553a0

Johan Z (1960) Koutekit - Cu2As, ein neues Mineral. Chem Erde 20: 217-226

Johan Z (1985) The Černý Důl deposit (Czechoslovakia): An example of Ni-, Fe-, Ag-, Cu-arsenide mineralization with extremely high activity of arsenic; new data on paxite, novakite and kutinaite. Tscherm Miner Petrogr Mitt 34: 167-182. https://doi.org/10.1007/bf01082960

Komínek J (1995) Geologie širšího okolí a vlastního ložiska. In: Závěrečná zpráva ložiska Příbram, Část I and II. MS DIAMO, Příbram, 418 s

Kranidiotis P, MacLean WH (1987) Systematics of chlorite alteration at the Phelps Dodge massive sulfide deposit, Matagami, Quebec. Econ Geol 82: 1898-1911. https://doi.org/10.2113/gsecongeo.82.7.1898  

Lafuente B, Downs RT, Yang H, Stone N (2015) The power of databases: the RRUFF project. In: Armbruster T, Danisi RM (eds.) Highlights in mineralogical crystallography, Berlin, Germany, W. De Gruyter 1-30. https://doi.org/10.1515/9783110417104-003  

Leroy J (1978) The Margnac and Fanay uranium deposits of the La Crouzille District (western Massif Central, France); geologic and fluid inclusion studies. Econ Geol 73: 1611-1634. https://doi.org/10.2113/gsecongeo.73.8.1611

Litochleb J, Černý P, Litochlebová E, Sejkora J, Šreinová B (2003) Ložiska a výskyty nerostných surovin v oblasti Středních Brd a Podbrdska. Bull Miner-petrolog Odd Nár Muz (Praha) 12: 57-86

Litochleb J, Sejkora J, Šrein V, Malec J (2009) Kašperskohorské zlato (Šumava, Česká republika). Bull mineral-petrolog odd Nár Muz (Praha) 17(1): 1-13

Makovicky M, Rose-Hansen J, Skinner BJ (1979) Phases and phase relations in the system Cu-Ag-As at 500°C, 400°C and 350°C. N Jb Mineral, Abh 135: 221-269

Malachov AA (1958) O vzniku willemitu v žíle Pošepného ve Vrančicích u Příbramě, Československo. Acta Univ Carol, Geol 3: 241-253 (rusky)

Malachov AA, Kouřimský J (1956) O výskytu willemitu ve Vrančicích u Milína. Rozpr Čs Akad Věd 66: 1-35

Martínek K, Blecha M, Daněk V, Franců J, Hladíková J, Johnová R, Uličný D (2006) Record of palaeoenvironmental changes in a Lower Permian organic-rich lacustrine succession: Integrated sedimentological and geochemical study of the Rudník member, Krkonoše Piedmont Basin, Czech Republic. Palaeogeogr Palaeoclimat Palaeoecol 230: 85-128. https://doi.org/10.1016/j.palaeo.2005.07.009

Morimoto N, Kato K (1970) Phase relations of the Cu-S system at low temperatures: stability of anilite. Am Mineral 55: 106-117

Mumme WG, Sparrow GJ, Walker GS (1988) Roxbyite, a new copper sulphide mineral from the Olympic Dam deposit, Roxby Downs, South Australia. Mineral Mag 52: 323-330. https://doi.org/10.1180/minmag.1988.052.366.03

Nickel EH (1987) Danielsite: A new sulfide mineral from Western Australia. Am Mineral 72: 401-403

Okrusch M, Lorenz JA, Weyer S (2007) The genesis of sulfide assemblages in the former Wilhemine mine, Spessart, Bavaria, Germany. Can Mineral 45: 723-750. https://doi.org/10.2113/gscanmin.45.4.723

Paar WH, Chen TT (1985) Zur Mineralogie von Cu-Ni-(Co)-Pb-Ag-Hg-Erzen in Revier Schwarzleo bei Leogang, Salzburg, Österreich. Mitt Österr geol Ges 78: 125-148

Picot P, Vernet J (1967) Un nouveau gisement de koutekite: le döme du Barrot (Alpes-Maritimes). Bull Soc franc Min Crist 90: 82-89. https://doi.org/10.3406/bulmi.1967.6070

Picot P, Ruhlmann F (1978) Presence d‘arseniures de cuivre de haute temperature dans le granite des Ballons (Vosges meddionales). Bull Mineral 101: 563-569. https://doi.org/10.3406/bulmi.1978.7229

Pierrot R, Picot P, Poulain PA (1972) Inventaire minéralogique de la France; Departement Hautes-Alpes 05. Orléans, BRGM, 184p

Poty B, Leroy J, Cathelineau M, Cuney M, Friedrich M, Lespinasse M, Turpin L (1986) Uranium deposits spatially related to granites in the French part of the Hercynian orogen. In: Fuchs HD (ed): Vein type uranium deposits. TECDOC- 361, IAEA, Vienna: 215-246

Pouchou JL, Pichoir F (1985) “PAP” (φρZ) procedure for improved quantitative microanalysis. In: Microbeam Analysis (J. T. Armstrong, ed.). San Francisco Press, San Francisco: 104-106

Raith JG, Leitner T, Paar WH (2015) Orogenic-type copper-gold-arsenic-(bismuth) mineralization at Flatschach (Eastern Alps), Austria. Mineral Petrol 109: 531-553. https://doi.org/10.1007/s00710-015-0391-5

Rule AC, Radke F (1988) Baileychlore, the Zn end member of the trioctahedral chlorite series. Am Mineral 73: 135-139

Sal’kov SA, Abulgazina SD (1990) First discovery of kutinaite in the USSR. Vest Akad Nauk Kazakh SSR 12: 81-82

Sejkora J, Škácha P, Kopecký S sen, Kopecký S jun, Pauliš P, Malíková R, Velebil D (2016) Se a Cu mineralizace z Bílé Vody u Javorníka (Česká republika). Bull mineral-petrolog Odd Nár Muz (Praha) 24(2): 161-177

Sejkora J, Škácha P, Dolníček Z (2019) Ag-Bi-Hg mineralization from the deposit Brod, uranium and base-metal ore district Příbram (Czech Republic). Bull Mineral Petrolog 27: 259-268

Sejkora J, Škácha P, Plášil J, Dolníček Z, Ulmanová J (2021) Hrabákite, Ni9PbSbS8, a new member of the hauchecornite group from Příbram, Czech Republic. Mineral Mag 85: 189-196. https://doi.org/10.1180/mgm.2021.1

Sejkora J, Dolníček Z, Zachariáš J, Ulmanová J, Šrein V, Škácha P (2022) Mineralogical and fluid inclusion evidence for reworking of Au mineralization by Ag-Sb-base metal-rich fluids from the Bytíz deposit, Příbram uranium and base-metal ore district, Czech Republic. Minerals 12(12): 1539. https://doi.org/10.3390/min12121539

Steiner M, Tropper P, Vavtar F, Kaindl R, Krismer M (2010) Balkanite from the Cu ore deposit Röhrerbühel, Kitzbühel (N-Tyrol, Austria). N Jb Mineral, Abh 187: 207-215. https://doi.org/10.1127/0077-7757/2010/0174

Škácha P, Sejkora J (2013) Výskyt cinnabaritu s mikroskopickým gortdrumitem na ložisku Vrančice u Příbrami (Česká republika). Bull mineral-petrolog odd Nár Muz (Praha) 21(1): 57-61

Tarkian M, Bock WD, Neurnann M (1983) Geology and mineralogy of the Cu-Ni-Co-U ore deposits at Talmessi and Meskani, Central Iran. Tscher Min Petr Mitt 32: 111-133. https://doi.org/10.1007/bf01081105

Trdlička Z, Hoffman V (1975) Untersuchungen der chemischen Zusammensetzung der Gangkarbonate von Kutná Hora (ČSSR). Freiberg Forschungshefte 6: 29-81

Ulmanová J, Dolníček Z, Škácha P, Sejkora J (subm.) Fluid inclusions in Zn-Pb mineralization of the vein Bt23C, Bytíz deposit, Příbram uranium and base-metal ore district, Czech Republic: the role of immiscible aqueous-carbonic fluids. Mineral Deposita submitted

Whelan JA, Goldich SS (1961) New data for hisingerite and neotocite. Am Mineral 46: 1412-1423

Žák K, Dobeš P (1991) Stable isotopes and fluid inclusions in hydrothermal deposits: the Příbram ore region. Rozpr ČSAV, ř mat přír věd: 1-109