ISSN
print 2570-7337
online 2570-7345
Hydrothermal bastnäsite-(Ce) from the Elisabeth adit near Gemerská Poloma (Slovak Republic)
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Abstract
Bastnäsite-(Ce), ideally CeCO3F, was recently found at the dumps of the Elisabeth adit near Gemerská Poloma, Rožňava Co., Košice Region, eastern Slovakia. It forms orange-brown aggregates up to 2 × 1 cm with vitreous to greasy lustre, which occur in the hydrothermal quartz veins crosscutting the coarse-grained, porphyritic rare metal S-type granite. Bastnäsite-(Ce) is closely associated with white, pale-green to purple fluorite, siderite and minor pyrite. It is hexagonal, space group P-62c with refined unit-cell parameters: a 7.1354(1) Å, c 9.7954(2) Å and V 431.90(1) Å3. The empirical formula of bastnäsite-(Ce) from the Gemerská Poloma based on sum of all cations = 1 apfu is (Ce0.49 La0.22Nd0.15Pr0.05Sm0.03Th0.02Ca0.02Gd0.01Y0.01)Σ1.00(CO3)1.00F0.83(OH)0.17. The Raman and infrared spectra of bastnäsite-(Ce) as well as tentative assignment of observed bands are given in this paper. Bastnäsite-(Ce) and associated minerals were formed from the early-hydrothermal post-magmatic fluids related to the adjacent granite.
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References
Adler HH, Kerr P F (1963) Infrared spectra, symmentry and structure relations of some carbonate minerals. Am Mineral 48(7-8): 839-853
Anders E, Grevesse N (1989) Abundances of the elements: Meteoritic and solar. Geochim Cosmochim Acta 53: 197-214. https://doi.org/10.1016/0016-7037(89)90286-X
Bačík P, Dianiška I, Števko M, Sečkár P (2011) Hnedý ihličkovitý dravit z mastencovo-magnezitového ložiska Gemerská Poloma (gemerikum, Slovensko). Bull mineral-petrolog Odd Nár Muz (Praha) 19(2): 164-170
Bajaník Š, Ivanička J, Mello J, Pristaš J, Reichwalder P, Snopko L, Vozár J, Vozárová A (1984) Geologická mapa Slovenského rudohoria, východná časť 1:50 000. ŠGÚDŠ, Bratislava
Bau M, Möller P (1992) Rare earth element fractionation in metamorphogenic hydrothermal calcite, magnesite and siderite. Miner Petrol 45: 231-246. https://doi.org/10.1007/BF01163114
Breiter K, Broska I, Uher P (2015) Intensive low-temperature tectono-hydrothermal overprint of peraluminous rare-metal granite: a case study from the Dlhá dolina valley (Gemericum, Slovakia). Geol Carpath 66(1): 19-36. https://doi.org/10.1515/geoca-2015-0008
Broska I, Kubiš M (2018) Accessory minerals and evolution of tin-bearing S-type granites in the western segment of the Gemeric Unit (Western Carpathians). Geol Carpath 59(5): 483-497. https://doi.org/10.1515/geoca-2018-0028
Broska I, Uher P (2001) Whole-rock chemistry and genetic typology of the West-Carpathian Variscan granites. Geol Carpath 52(2): 79-90
Burnham ChW (1962) Lattice constant refinement. Carnegie Inst Washington Year Book 61: 132-135
Čejka J, Sejkora J, Jebavá I, Xi Y, Couperthwaite SJ, Frost RL (2013) A Raman spectroscopic study of the basic carbonate mineral callaghanite Cu2Mg2(CO3)(OH)6·2H2O. Spectrochim Acta A, Mol Biomol Spectrosc 108: 171-176. https://doi.org/10.1016/j.saa.2013.01.033
Dianiška I, Breiter K, Broska I, Kubiš M, Malachovský P (2002) First phosphorous-rich Nb-Ta-Sn-specialised granite from the Carpathians-Dlhá dolina valley granite pluton, Gemeric super-unit. Geol Carpath 53 Special Issue (CD ROM). https://doi.org/10.1515/geoca-2015-0008
Dolníček Z, Ulmanová J (2019): Mineralogická charakteristika dvou typů hydrotermálních žil s obsahem REE minerálů z lomu u Vrbčan (kutnohorské krystalinikum). Bull Mineral Petrolog 27(2): 331-345
Donnay G, Donnay JDH (1953) The crystallography of bastnaesite, parisite, roentgenite, and synchisite. Am Mineral 38(11-12): 932-963
Frost RL, Dickfos MJ (2007) Raman spectroscopy of halogen-containing carbonates. J Raman Spectrosc 38: 1516-1522. https://doi.org/10.1002/jrs.1806
Grecula P, Kobulský J, Gazdačko Ľ, Németh Z, Hraško Ľ, Novotný L, Maglay J (2009) Geologická mapa Spišsko-gemerského rudohoria 1:50 000. ŠGÚDŠ, Bratislava
Chukanov NV (2014) Infrared spectra of mineral species: extended library. Vol. 1. Springer Dordrecht
Kilík J (1997) Geologická charakteristika mastencového ložiska Gemerská Poloma-Dlhá dolina. Acta Montan Slovaca 2(1): 71-80
Kilík J, Bachňák M, Mihalík F, Stupák J, Palcso A (1995) Záverečná správa a výpočet zásob úlohy Gemerská Poloma, mastenec, VP. Stav k 31.3.1995. MS, archív ŠGÚDŠ-Geofond, Bratislava, 214, 79885
Kubiš M, Broska I (2010) The granite system near Betliar village (Gemeric Superunit, Western Carpathians): evolution of a composite silicic reservoir. J Geosci 55(2): 131-148. http://dx.doi.org/10.3190/jgeosci.066
Lee SG, Lee DH, Kim Y, Chae BG, Kim WY, Woo NCh (2003) Rare earth elements as indicators of groundwater environment changes in a fractured rock system: evidence from fracture – filling calcite. Appl Geoch 18: 135-143. https://doi.org/10.1016/S0883-2927(02)00071-9
Libowitzky E (1999) Correlation of O-H stretching frequencies and O-H´´´O hydrogen bond lengths in minerals. Monat Chem 130(8): 1047-1059. https://doi.org/10.1007/BF03354882
Malachovský P, Dianiška I, Matula I (1983) Záverečná správa, SGR-vysokotermálna mineralizácia - VP, Sn, W, Mo rudy. Stav k 18.8.1983. MS, archív ŠGÚDŠ-Geofond, Bratislava, 248, 56500
Malachovský P, Dianiška I, Varga I (1992) Gemerská Poloma, Sn - záverečná správa, stav k 30.11.1990. MS, archív ŠGÚDŠ-Geofond, Bratislava, 187, 78404
McLennan SM (1989) Rare earth elements in sedimentary rocks: influence of provenance and sedimentary processes. Rev Mineral 21: 169-200. https://doi.org/10.1515/9781501509032
Michiba K, Miyawaki R, Minakawa T, Terada Y, Nakai I, Matsubara S (2013) Crystal structure of hydroxylbastnäsite-(Ce) from Kamihouri, Miyazaki Prefecture, Japan. J Mineral Petrolog Sci 108(6): 326-334. https://doi.org/10.2465/jmps.121129
Nakamoto K (2009) Infrared and Raman spectra of inorganic and coordination compounds Part A: Theory and applications in inorganic chemistry. John Wiley and Sons, Hoboken, New Jersey
Ni Y, Hughes JM, Mariano AN (1993) The atomic arrangement of bastnäsite-(Ce), Ce(CO3)F, and structural elements of synchysite-(Ce), röntgenite-(Ce), and parisite-(Ce). Am Mineral 78(3-4): 415-418
Oftedal I (1931) Zur Kristallstruktur von Bastnäsit (Ce,La--)FCO3. Z Kristallogr 78: 462-469. https://doi.org/10.1524/zkri.1931.78.1.462
Ondrejka M, Uher P, Pršek J, Ozdín D (2007) Arsenian monazite-(Ce) and xenotime-(Y), REE arsenates and carbonates from the Tisovec-Rejkovo rhyolite, Western Carpathians, Slovakia: Composition and substitutions in the (REE,Y)XO4 system (X = P, As, Si, Nb, S). Lithos 95: 116-129. https://doi.org/10.1016/j.lithos.2006.07.019
Ondrejka M, Uher P, Putiš M, Broska I, Bačík P, Konečný P, Schmiedt I (2012) Two-stage breakdown of monazite by post-magmatic and metamorphic fluids: An example from the Veporic orthogneiss, Western Carpathians, Slovakia. Lithos 142-143: 345-255. https://doi.org/10.1016/j.lithos.2012.03.012
Ondrejka M, Putiš M, Uher P, Schmiedt I, Pukančík L, Konečný P (2016) Fluid-driven destabilization of REE-bearing accessory minerals in the granitic orthogneisses of North Veporic basement (Western Carpathians, Slovakia). Miner Petrol 110(5): 561-580. https://doi.org/10.1007/s00710-016-0432-8
Ondruš P (1993) ZDS - A computer program for analysis of X-ray powder diffraction patterns. Materials Science Forum, 133-136, 297-300, EPDIC-2. Enchede. https://doi.org/10.4028/www.scientific.net/MSF.133-136.297
Petrasová K, Faryad SW, Jeřábek P, Žáčková E (2007) Origin and metamorphic evolution of magnesite-talc and adjacent rocks near Gemerská Poloma, Slovak Republic. J Geosci 52(1-2): 125-132. http://dx.doi.org/10.3190/jgeosci.001
Poller U, Uher P, Broska I, Plašienka D, Janák M (2002) First Permian-Early Triassic zircon ages for tin-bearing granites from the Gemeric Unit (Western Carpathians, Slovakia): connection to the post-collisional extension of the Variscan orogen and S-type granite magmatism. Terra Nova 14: 41-48. https://doi.org/10.1046/j.1365-3121.2002.00385.x
Pouchou JL, Pichoir F (1985) “PAP” (φρZ) procedure for improved quantitative microanalysis. In: Microbeam Analysis (J. T. Armstrong, ed.). San Francisco Press, San Francisco, 104-106
Števko M, Sejkora J, Uher P, Cámara F, Škoda R, Vaculovič T (2018) Fluorarrojadite-(BaNa), BaNa4CaFe13 Al(PO4)11(PO3OH)F2, a new member of the arrojadite group from Gemerská Poloma, Slovakia. Mineral Mag 82(4): 863-876. https://doi.org/10.1180/minmag.2017.081.066
Števko M, Uher P, Sejkora J, Malíková R, Škoda R, Vaculovič T (2015) Phosphate minerals from the hydrothermal quartz veins in specialized S-type granites, Gemerská Poloma (Western Carpathians, Slovakia). J Geosci 60(4): 237-249. http://dx.doi.org/10.3190/jgeosci.202
Uher P (1994) REE minerály v granitoch upohlavského typu (pieninské bradlové pásmo). Miner Slov Geovestník 26(5): 10
Uher P, Broska I (1996) Post-orogenic Permian granitic rocks in the Western Carpathian-Pannonian area: geochemistry, mineralogy and evolution. Geol Carpath 47(5): 311-321
Uher P, Malachovský P, Bačík P, Chudík P, Števko M (2009) Polykras-(Y), uranopolykras a Ti-Nb-Ta-Fe minerál v kremenných žilách a exokontaktných zónach granitov gemerika, Slovenské rudohorie. Bull mineral-petrolog Odd Nár Muz (Praha) 17(1): 14-24
Uher P, Malachovský P, Ondrejka M, Pršek J (2010) Zr-REE-Nb mineralization in metatrachydacites of the Rakovec group (Gemeric Superunit, Western Carpathians, Slovakia): A product of interaction between host-rock and F-, CO2-rich fluids. Z geol Wiss 38(2-3): 167-179
Uher P, Ondrejka M, Bačík P, Broska I, Konečný P (2015) Britholite, monazite, REE carbonates, and calcite: Products of hydrothermal alteration of allanite and apatite in A-type granite from Stupné, Western Carpathians, Slovakia. Lithos 236-237: 221-225. https://doi.org/10.1016/j.lithos.2015.09.005
Yang H, Dembowski RF, Conrad PG, Downs RT (2008) Crystal structure and Raman spectrum of hydroxyl-bastnasite-(Ce), CeCO3(OH). Am Mineral 93(4): 698-701. https://doi.org/10.2138/am.2008.2827
Yvon K, Jeitschko W, Parthé E (1977) Lazy Pulverix, a computer program for calculation X-ray and neutron diffraction powder patterns. J Appl Cryst 10: 73-74. https://doi.org/10.1107/s0021889877012898