Zeolite mineralization from Nový Oldřichov near Kamenický Šenov (Czech Republic)
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Abstract
An interesting zeolite association has been found at several outcrops of North-Bohemian kenozoic alkaline volcanics close the Nový Oldřichov village near Kamenický Šenov (northern Bohemia, Czech Republic). Offretite is the most interesting zeolite at these occurrences, it forms colorless acicular crystals up to 1.5 mm in size and hemispherical aggregates up to 3 mm accross. Epitaxial overgrowths of chabazite by tiny acicular offretite crystals were also observed. Offretite is hexagonal, space group P-6m with following unit-cell parameters refined from the powder X-ray data: a 13.295(6), c 7.6133(4) Å and V = 1165.4(6) Å3. Its chemical analyses correspond to the empirical formula K1.02Ca.1.39Mg0.51Sr0.04 (Si12.87Al5.21)O36·15H2O. Chabazite-Ca, chabazite-K, phillipsite-Ca and phillipsite-K were found in the association with offretite; their X-ray powder diffraction data, refined unit-cell parameters and chemical compositions are given in the paper.
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References
Betz V., Hentschel G. (1978) Offretit und Erionit von Gedern (Vogelsberg). Geol. Jb. Hessen 106, 419-421.
Coombs D. S., Alberti A., Armbruster T., Artioli G., Colella C., Galli E., Grice J. D., Liebau F., Mandarino J. A., Minato H., Nickel E. H., Passaglia E., Peacor D. R., Quartieri S., Rinaldi R., Ross M., Sheppard R. A., Tillmanns E., Vezzalini G. (1997) Recommended nomenclature for zeolite minerals: report of the subcommittee on zeolites of the International Mineralogical Association, commission on new minerals and mineral names. Can. Mineral. 35, 1571-1606.
Deer W. A., Howie R. A., Wise W. S., Zussman J. (2004) Rock-forming Minerals, Framework Silicates: Silica Minerals, Feldspathoids and the Zeolites. Vol. 4B. The Geological Society London.
Gatta G. D., Cappelletti P., Rotiroti N., Slebodnick C., Rinaldi R. (2009) New insights into the crystal structure and crystal chemistry of the zeolite phillipsite. Am. Mineral. 94, 190-199.
Gualtieri A., Artioli G., Passaglia E., Bigi S., Viani A., Hanson J. C. (1998) Crystal structure - crystal chemistry relationships in the zeolites erionite and offretite. Am. Mineral. 83, 590-606.
Hibsch J. E. (1927): Erläuterungen zur geologischen Karte der Umgebung von Böhm.Kamnitz. Knihovna Statního geologického ústavu Československé republiky, Svazek 10, SGÚ ČSR, Praha.
Kolektiv (2013) Kdysi Mistrovice, dnes Nový Oldřichov. Rema 93, Česká Lípa. 192 s.
Kratochvíl J. (1957-1966): Topografická mineralogie Čech I. - VIII. NČSAV, Praha.
Laugier J., Bochu B. (2011) LMGP-Suite of Programs for the Interpretation of X-ray Experiments. http://www.ccp14.ac.uk/tutorial/lmgp, přístup duben 2011.
Passaglia E., Tagliavini A. (1994) Chabazite-offretite epitaxial overgrowths in cornubianite from Passo Forcel Rosso, Adamello, Italy. Eur. J. Mineral. 6, 397-405.
Pauliš P., Svejkovský J., Janeček O., Hrůzek L., Dvořák Z., Jebavá I. (2013) Offretit kamenolomu Vrbička u Valče v Doupovských horách. Bull. mineral.-petrolog. Odd. Nár. Muz.(Praha) 21, 2, 171-178.
Pauliš P., Hrůzek L., Janeček O., Sejkora J., Malíková R. (2014) Cowlesit a doprovodná mineralizace z vrchu Hackenberg u České Kamenice (Česká republika). Bull. mineral.-petrolog. Odd. Nár. Muz. (Praha) 22, 2, 248-260.
Pauliš P., Hrůzek L., Janeček O., Dvořák Z., Toman J., Svejkovský J., Radoň M. (2015a) Nejzajímavější mineralogická naleziště Čech - zeolity a doprovodná mineralizace. Kuttna, Kutná Hora. 280 s.
Pauliš P., Hrůzek L., Janeček O., Sejkora J., Malíková R., Pour O., Fediuk F. (2015b) Tschernichit, garronit-Ca a doprovodná zeolitová mineralizace z Jehly u České Kamenice (Česká republika). Bull. mineral.-petrolog. Odd. Nár. Muz. (Praha) 23, 2, 147-170.
Pouchou J. L., Pichoir F. (1985) “PAP” (φρZ) procedure for improved quantitative microanalysis. In: Microbeam Analysis (J. T. Armstrong, ed.). San Francisco Press, San Francisco, 104-106.
Rychlý R., Daněk M. (1981) Wellsit a offretit-erionit z Prackovic nad Labem. Čas. Mineral. Geol. 26, 431-432.
Řídkošil T., Daněk M. (1983) New physical and chemical data for levyne-offretite intergrowths from Žežice near Ústí nad Labem, Czechoslovakia. N. Jb. Mineral., Abh., 1, 99-108.
Tschernich R. W. (1992) Zeolites of the world. Geoscience Press, Phoenix.
Veselovský F., Rychlý R. (1988) Offretit a harmotom z lokality Stupná u Nové Paky. Čas. Mineral. Geol. 33, 1, 109-110.
Yakubovich O. V., Massa W., Gavrilenko P. G., Pekov I. V. (2005) Crystal structure of chabazite. Kristallografiya 50, 4, 595-604.