Bulletin Mineralogie Petrologie

Ferenc Štefan, Biroň Adrián, Luptáková Jarmila, Mikuš Tomáš

Ročník 24, číslo 2 (2016), strana 256-268

zeolite, laumontite, heulandite-Ca, basalts, Permian, zeolite facies metamorphism, Hronicum Unit, Slovak Republic

Laumontite and heulandite-Ca were found in the cracks and cavities of Permian basalt (Malužiná Formation, Ipoltica Group of the Hronicum Unit), in the eastern part of the Kozie Chrbty Mts., at Spišská Teplica - Štefánikova and Lučivná - Lopušná Dolina localities. Laumontite has a relatively monotonous chemical composition, only K content reaches up to 0.75 apfu. Average crystallochemical formula of laumontite (both occurrences) is (K_0.41Na_0.06Ca_3.61)_Σ4.08[Si_16.03Al_7.54]_Σ23.56O₄₈·18H₂O, Si/Al ratio 2.13. Main diffraction maxima d(I) of laumontite are 9.461(100), 6.844(44), 4.157(48), 3.508(33), 3.272(22), unit cell parameters: a = 14.738(1) Å, b = 13.087(1) Å, c = 7.554(1) Å, β = 111.84°, V = 1352.3 ų. Ca is dominant component in heulandite-Ca from the Štefánikova occurrence (2.18-2.69 apfu), from other admixtures, significantly increased is K content (1.30-2.35 apfu). Less important are Ba (0.05-0.7 apfu) and Sr (0.23-0.60 apfu), Na content reached up to 0.26 apfu. Average chemical composition of studied heulandite-Ca corresponds to formula (K_1.79Na_0.16Ca_2.39Ba_0.38Sr_0.39Fe_0.13)_Σ5.24[Si_26.82Al_8.94]_Σ35.76O₇₂·24H₂O, Si/Al ratio 3.00. Its main diffraction maxima d(I) are 8.954(100), 4.650(17), 3.976(18), 3.897(18), 2.973(37), unit cell parameters: a = 17.786(1) Å, b = 17.930(1) Å, c = 7.4338(1) Å, β = 115.93°, V = 2131.9 ų. Zeolites probably originated during the Alpine orogeny, at the reduced p-T conditions after a peak of the prehnite-pumpellyite facies of basalt metamorphosis. The minimum estimated conditions of their origin are T ~ 210 °C and p 2.1-2.4 kbar, corresponding to the burial depth of Hronicum basalts around 7 km, in the time of zeolites formation.

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