Retgersit z ložiska Rudňany (Slovenská republika)
Retgersite from the Rudňany deposit (Slovak Republic)
Klíčová slova
Abstrakt
A relatively rare hydrated sulphate of Ni, retgersite, was identified on the ore samples originating from the crosscut P-3, located on the 16th level of the Zlatník vein, Rudňany deposit, Slovak Republic. Retgersite is rare and occurs on the surface of fragments of siderite gangue with abundant aggregates of coarse-grained gersdorffite. It forms light blue to blue-green, often curved fibrous to crystalline aggregates up to 3 mm in size with vitreous lustre, which are grouped to rich crust and efflorescences growing directly on surface of gersdorffite. Retgersite was identified by PXRD and its refined unit-cell parameters (for the tetragonal space group P41212) are: a 6.7820(5) Å, c 18.281(2) Å and V 840.8(1) Å3. Results of semiquantitative chemical analysis (EDS) as well as vibrational spectra (Raman, infrared) including their tentative assignments are also given. Retgersite from the Rudňany deposit was formed as a product of post-mining decomposition of gersdorffite.
Soubory
Reference
Angel RJ, Finger LW (1988) Polymorphism of nickel sulfate hexahydrate. Acta Cryst C 44(11): 1869-1873
Bernard JH (1955) K sukcesi minerálů rudní žíly Droždiak v Rudňanech. Věst Ústř Úst geol (Praha) 30: 237-239
Bernard JH (1961) Mineralogie und Geochemie der Siderit-Schwerspatgänge mit Sulfiden im Gebiet von Rudňany (Tschechoslowakei). Geol Práce 58: 1-222
Burnham Ch W (1962) Lattice constant refinement. Carnegie Inst Washington Year Book 61: 132-135
Cambel B, Jarkovský J, Faith L, Forgáč J, Hovorka D, Hrnčárová M, Hurný J, Ivan P, Karoli A, Kráľ J, Litavec J, Matula I, Mihalov J, Popreňák J, Rényi K, Rojkovič I, Rozložník L, Sasvári T, Savčenková L, Spišiak J, Šmejkal V, Turan J, Turanová L, Varček C, Žabka M, Žukov F (1985) Rudnianské rudné pole. Veda, Bratislava, 1-363
Fehér B, Szakáll S, Kristálly F, Zajzon N (2016) Mineralogical mosaics from the Carpathian-Pannonian region 3. Föld Közl 146(1): 47-60
Frondel C, Palache C (1949) Retgersite, NiSO4·6H2O, a new mineral. Am Mineral 34(3-4): 188-194
Grecula P, Abonyi A, Abonyiová M, Antaš J, Bartalský B, Bartalský J, Dianiška I, Ďuďa R, Gargulák M, Gazdačko Ľ, Hudáček J, Kobulský J, Lörincz L, Macko J, Návesňák D, Németh Z, Novotný L, Radvanec M, Rojkovič I, Rozložník L, Varček C, Zlocha Z (1995) Ložiská nerastných surovín Slovenského rudohoria. Zväzok 1. Geocomplex, Bratislava, 1-834
Hurný J, Krištín J (1978) Niektoré Ni-Co-minerály z ložiska Rudňany (žila Zlatník). Miner Slov 10(3): 221-238
Chukanov NV (2014) Infrared spectra of mineral species: extended library. Vol. 2. Springer Dordrecht
Libowitzky E (1999) Correlation of O-H stretching frequencies and O-H´´´O hydrogen bond lengths in minerals. Monat Chem 130: 1047-1059
Mikuš T, Chovan M (2007) Retgersit z Čiernej Lehoty (Strážovské vrchy). Miner Slov 39(3): 197-203
Nakamoto K (2009) Infrared and Raman spectra of inorganic and coordination compounds Part A: Theory and application in inorganic chemistry. John Wiley and Sons, Hoboken New Jersey
Ondruš P (1993) ZDS - A computer program for analysis of X-ray powder diffraction patterns. Materials Science Forum, 133-136, 297-300, EPDIC-2. Enchede
Petrova EV, Vorontsova MA, Manomenova VL, Rashkovich LN (2012) Some properties of aqueous solutions of α-NiSO4· 6H2O. Crystallogr Rep 57(4): 579-584
Rojkovič I (1977) Mineralogicko-geochemické štúdium opaktných minerálov na ložisku Rudňany. Manuskript, archív ŠGÚDŠ, Bratislava, 1-224
Ross SD (1974) Chapter 18. Sulphates and other oxy-anions of Group VI. In: The Infrared Spectra of Minerals (Ed.: V. C. Farmer), 423-444. The Mineralogical Society, London
Rousseau B, Maes ST, Lenstra AT (2000) Systematic intensity errors and model imperfection as the consequence of spectral truncation. Acta Cryst A 56(3): 300-307
Sejkora J (1992) Retgersit ze Smrkovce u Mariánských Lázní. Čas Mineral Geol 37(4): 79
Sejkora J, Plášil J (2009) Mineralien aus dem Uranrevier Horni Slavkov. Lapis 34 (7-8): 63-67; 70
Sejkora J, Řídkošil T (1993) Retgersite from Jáchymov, Krušné hory Mountains, Czech Republic. N Jb Mineral, Mh (9): 393-400
Stadnicka K, Glazer AM, Koralewski M (1987) Structure, absolute configuration and optical activity of α-nickel sulfate hexahydrate. Acta Cryst B 43(4): 319-325
Števko M, Peterec D, Turecký L, Kráčmar L (2017a) Prehľad zberateľsky atraktívnych minerálov z ložiska Rudňany. Minerál 25(1): 28-48
Števko M, Dojčanský Ľ, Volejník M, Sejkora J (2017b) Nový nález sekundárnych minerálov na Hrubej žile v Rudňanoch. Minerál 25(1): 87-93
Vozárová A, Vozár J (1988) Late Paleozoic in West Carpathians. GÚDŠ, Bratislava, 1-314
Yvon K, Jeitschko W, Parthé E (1977) Lazy Pulverix, a computer program for calculation X-ray and neutron diffraction powder patterns. J Appl Cryst 10: 73-74