Bulletin Mineralogie Petrologie

Ferenc Štefan, Vlasáč Jozef, Mikuš Tomáš, Šimonová Viera, Olšavský Mário

Ročník 27, číslo 1 (2019), strana 46-62

quartz-sulphidic mineralization, Cu-Pb-Sb-As sulphosalts, seligmannite, tetrahedrite, tennantite, sulphoarsenides, Veporic Unit, Western Carpathians

Ľubietová-Peklo Cu-(±Ag) ore occurrence is located about 20 km to the E from Banská Bystrica (district city) and about 3.7 km to the ENE from Ľubietová village (Central Slovakia). In the past (16^th - 19^th century), mining works of a lesser extent were made on this site. Subvertical quartz-carbonate veins (NE-SW to E-W direction) with ore minerals intersect both, migmatitised orthogneisses (Lower Paleozoic) and Permian greywackes of the Veporic Unit. Ore veins are intersected and displaced by NW-SE directed younger tectonic structures (often with development of quartz veins without ore mineralization). Ore mineralization originated in the following stages: I.) pyrite-arsenopyrite stage (quartz I, pyrite, arsenopyrite, cobaltite I); II.) bournonite stage (bournonite-seligmannite, galena); III) carbonate stage (dolomite-Fe dolomite, barite) and quartz-sulphidic stage (quartz II, cobaltite II, sphalerite, chalcopyrite I and II, tetrahedrite, tennantite). Supergene zone is represented by small amounts of cerussite, malachite and goethite. Mineralogically remarkable are zonal crystals of bournonite-seligmannite (almost complete solid solution). The most extreme difference between As and Sb content in a single crystal can be expressed as Bnn₉₉Slg₁ to Slg₈₄Bnn₁₆. The Sb content generally increases from the centre of the crystals toward their rims. On the most deposits, mineral phases of the bournonite-seligmannite series occur as a younger minerals (in association with jordanite, geocronite and galena) and crystallize usually after precipitation of tetrahedrite, tennantite, or chalcopyrite. As for the Ľubietová-Peklo occurrence, mineral phases of bournonite-seligmannite series crystallize directly from As- and Sb-bearing hydrothermal fluids, unusually before crystallization of tetrahedrite, tennantite and chalcopyrite. Hydrothermal vein mineralization has an Alpinian age and originated most probably during Upper Cretaceous.

Abstrakt (PDF) - 199.23KB
Fulltext (PDF) - 2.17MB

Apopei AI, Damian G, Buzgar N, Buzatu A (2016) Mineralogy and geochemistry of Pb-Sb/As-sulfosalts from Coranda-Hondol ore deposit (Romania) - Conditions of telluride deposition. Ore Geol Rev 72: 857-873

Avchenko OV, Vakh AS, Chudnenko KV (2015) Thermobarometry of mineral equilibriums in metasomatites and meta-porphyrites from the Berezitovoe ore deposit (Upper Priamurye). Bull Kamchatka Reg Asoc, Earth Sci 25: 231-236

Baumhauer H (1901) Über den Seligmannit, ein neues dem Bournonit homomorphes Mineral aus dem Dolomit des Binenthales. Sitzunsber. deut. Akad. Wiss. Berlin 6: 110-117

Bergfest A (1951) Baníctvo v Ľubietovej na medenú rudu (I.-III.). MS, archív ŠGÚDŠ - Geofond Bratislava AP 3668

Besu K, Bortnikov NS, Mukerji A, Mozgova NN, Tsepin AI (1984) Mineralogical and geochemical features of the Rajpura-Dariba stratimorphic polymetallic deposit. The geology and minerals of ancient platforms (Moscow), 99-105. Nauka Moscow (rusky)

Bezák V, Broska I, Konečný P, Petrík I, Košler J (2008) Permský magmatický komplex v severnom veporiku: interpretácia z nových datovaní kyslých magmatitov. Miner Slov 40: 127-134

Bláha M, Hauerová J, Bartoň B, Linkešová M, Fodorová V, Makuša M, Dvoršťák J, Pitoňák P, Spišiak J, Vybíral V, Okáľ B, Obst P (1989) Ľubietová - Kolba, Záverečná správa. MS, archív ŠGÚDŠ - Geofond, Bratislava AP 74 660

Buzatu A, Damian G, Dill HG, Buzgar N, Apopei AI (2015) Mineralogy and geochemistry of sulfosalts from Baia Sprie ore deposit (Romania) - New bismuth minerals occurrence. Ore Geol Rev 65: 132-147

Ciobanu CL, Cook NJ, Capraru N, Damian G, Cristea P (2005) Mineral assamblages from the vein salband at Sacarimb, Golden quadrilateral, Romania: I. Sulphides and sulphosalts. Geochem Mineral Petrolog 43: 47-55

Cook NJ (1996) Mineralogy of the sulphide deposits at Sulitjelma, northern Norway. Ore Geol Rev 11: 303-338

Cook NJ, Spry PG, Vokes FM (1998) Mineralogy and textural relationships among sulphosalts and related minerals in the Bleikvassli Zn-Pb-(Cu) deposit, Nordland, Norway. Miner Depos 34: 35-56

Ferenc Š, Bakos F, Demko R, Koděra P (2014) Výskyty sideritovej (Fe karbonátovej) a kremeňovo-sulfidickej minera­lizácie pri Lovinobani a Uderinej (Slovenské rudohorie-veporikum), Slovenská republika. Bull mineral-petrolog Odd Nár Muz (Praha) 22: 25-41

Harris DC (1989) The mineralogy and geochemistry of the Hemlo gold deposit, Ontario. 1-88, Canadian Government Publishing Centre, Ottawa

Hofmann BA, Knill MD (1996) Geochemistry and genesis of the Lengenbach Pb-Zn-As-Tl-Ba mineralisation, Binn valley, Switzerland. Miner Depos 31: 319-339

Hurai V, Lexa , Schulmann K, Montigny R, Prochaska W, Frank W, Konečný P, Kráľ J, Thomas R, Chovan M (2008) Mobilization of ore fluids during Alpine metamorphism: evidence from hydrothermal veins in the Variscan basement of Western Carpathians, Slovakia. Geofluids 8: 181-207

Hvožďara M (1980) Prospekčné minerály tatroveporidného kryštalinika. Acta Geol Geogr Univ Comen, Geol 35: 5-43

Kamenický J (1977) Der geologische bau der nordwestlichen teiles der Vepor-erzgebirges. Acta Geol Geogr Univ Comen, Geol 32: 5-43

Kamenický J (1982a) Petrografia ortorúl a pararúl, synkinematických migmatitov a ich diaftoritov v severozápadnej časti Veporského rudohoria. Miner Slov 6: 481-516

Kamenický J (1982b) Vývoj a podmienky metamorfózy v severozápadanej časti Slovenského rudohoria. In Krist E, Mihalíková A (eds.) Metamorfné procesy v Západných Karpatoch 23-37. GÚDŠ, Bratislava

Luptáková J, Milovská S, Jeleň S, Mikuš T, Milovský R, Biroň A (2016) Primary ore Cu mineralization at the Ľubietová-Podlipa locality (Slovakia). Acta Geol Slov 8: 175-194

Maheľ M, Kamenický J, Fusán O, Matějka A (1967) Regionální geologie ČSSR, díl II - Západní Karpaty. 1-486, Academia, nakl. ČSAV, Praha

Mikaeili K, Hosseinzadeh MR, Moayyed M, Maghfouri S (2018) The Shah-Ali-Beiglou Zn-Pb-Cu-(Ag) deposit, Iran: An example of intermediate sulfidation epithermal type mineralization. Minerals DOI:10.3390/min8040148

Planderová E, Vozárová A (1982) Biostratigraphical correlation of the Late Paleozoic formations in the West Carpathians. In: Sassi FP, Varga I (eds.) Newsletter No. 4, IGCP Project No. 5, 61-71

Polák M, Filo I, Havrila M, Bezák V, Kohút M, Kováč P, Vozár J, Mello J, Maglay J, Elečko M, Olšavský M, Pristaš J, Siman P, Buček S, Hók J, Rakús M, Lexa J, Šimon L (2003a) Geologická mapa Starohorských vrchov, Čierťaže a severnej časti Zvolenskej kotliny, M 1: 50 000. MŽP SR - ŠGÚDŠ, Bratislava

Polák M, Filo I, Havrila M, Bezák V, Kohút M, Kováč P, Vozár J, Mello J, Maglay J, Elečko M, Olšavský M, Pristaš J, Siman P, Buček S, Siráňová Z, Hók J, Rakús M, Lexa J, Šimon L, Pristaš J, Kubeš P, Zakovič M, Liščák P, Žáková E, Boorová D, Vaněková H (2003b) Vysvetlivky ku geologickej mape Starohorských vrchov, Čierťaže a severnej časti Zvolenskej kotliny, M 1: 50 000. 1-218, ŠGÚDŠ, Bratislava

Robl K, Brodtkorb MK, Ametrano S (2009) La mineralización epitermal miocena del complejo estratovolcánico Quevar, Salta. Revista de la Asociación Geológica Argentina 64: 525-539

Rosenberg JL, Spry PG, Jacobson CE (1998) Thermobarometry of the Bleikvassli Zn-Pb-(Cu) deposit, Nordland, Norway. Miner Depos 34: 19-34

Rybár P, Hronček P (2016) Historical blast furnace in Peklo valley of Ľubietová (Slovakia) and its reconstruction using 3D modelling. Acta Mont Slov 21: 333-341

Serafimovski T, Tasev G (2003) The Plavica epithermal polymetallic system: mineralogical and geochemical data. Vol 1. Proceedings from the conference Mineral exploration and sustainable development (Athens): 523-526. Milpress Rotterdam

Slavkay M, Beňka J, Bezák V, Gargulák M, Hraško Ľ, Kováčik M, Petro M, Vozárová A, Hruškovič S, Knésl J, Knéslová A, Kusein M, Maťová V, Tulis J (2004) Ložiská nerastných surovín Slovenského rudohoria, Vol. 2. 1-286, ŠGÚDŠ, Bratislava

Slavkay M, Knésl J, Čillík I, Bláha M, Biely A, Vybíral V, Maar S, Beňka J (1990) Regionálna mapa ložísk a prognóz rudných surovín okolia Banskej Bystrice, M 1 : 50 000. MS, archív ŠGÚDŠ - Geofond, Bratislava AP 75 270

Slavkay M, Petro M (1993): Metalogenéza a rudné formácie veporika. Miner Slov 25: 313-317

Spišiak J, Siman P (2014) Geochemistry of the granite porphyry from Ľubietová crystalline complexes (Western Carpathians). Zbor konf CEMC 2014 (Skalský Dvůr), 132-133. Masarykova Univerzita - Česká Geologická Společnosť, Brno

 ŠGÚDŠ (2013) Geologická mapa Slovenska M 1:50 000 (online). Bratislava: Štátny geologický ústav Dionýza Štúra, 2013. Prístup. 28. 11. 2018 na adrese http://apl.geology.sk/gm50js

Taug J (1827) Karte uiber den in der Grössen Hölle des Brusnaer Thales bestehenden Joannis Schachter Bergbau, in Verbindung mit den nach verfindigen alten augentafsenen Stölln. MS, archív ŠÚBA - Banská Štiavnica AP 9225

Tomkins AG, Frost BR, Pattison DRM (2006) Arsenopyrite melting during metamorphism of sulfide ore deposits. Can Mineral 44: 1045-1062

Tomkins AG, Pattison DRM, Zaleski E (2004) The Hemlo Gold deposit, Ontario: An example of melting and mobilization of a precious metal-sulfosalt assemblage during amphibolite facies metamorphism and deformation. Econ Geol 99: 1063-1084

Vakh AS, Avchenko OV, Goryachev NA, Gvozdev VI, Karabtsev AA, Vakh EA (2017) Minerals of the bournonite-seligmannite series in ore of the Beresitovoe deposit, Upper Amur region, Russia. Geol Ore Dep 59: 738-744

Varček C (1985) Charakteristika metalogenézy Spišsko-gemerského rudohoria a postavenie rudnianskeho rudného poľa. In Cambel B (ed.) Rudnianske rudné pole: 61-77. Veda, vydavateľstvo SAV, Bratislava

Vozárová A (1979) Litofaciálna charakteristika permu v severozápadnej časti veporika. Západ Karpaty, Sér Mineral Petrogr Geochém Metalogen 8: 143-199

Vozárová A, Lepekhina E, Vozár J, Rodionov N (2010) In situ U-Pb (SHRIMP) zircon age dating from the Permian volcanites of the Northern Veporicum. Conference Proceedings Dating 2010 (Bratislava): 49. ŠGÚDŠ Bratislava.

Vozárová A, Rodionov N, Vozár J, Lepekhina E, Šarinová K (2016) U-Pb zircon ages from Permian volcanic rocks and tonalite of the Northern Veporicum (Western Carpathians). J Geosci 61: 221-237

Zoubek V (1936) Poznámky o krystaliniku Západních Karpat. Věst Stát Geol Úst ČSR 12: 207-239

Zoubek V (1958) Postkinematické granitoidy tatro-veporského intruzívneho komplexu. MS, archív ŠGÚDŠ - Geofond Bratislava AP 3744

Zsemley O (1904) Libetbánya multja. Bányászati és Kohászati Lapok 39: 405-407