Study of phosphate and sulphate association from the Mine No. 6 “Exi” in the Lavrion mining district (Greece): chemistry and PXRD data
Keywords
Abstract
A large number of supergene minerals has been identified in the Lavrion mining district (Greece). The dominant part belongs to the group of arsenates or sulphates. The substitution of phosphorus for arsenic or the occurrence of phosphates is relatively rare at this mining district. The new occurrence of the association of supergene phosphates including phosphosiderite, mitridatite, jahnsite-(NaFeMg), fluorapatite and collinsite, in association with minerals of the alunite group, jarosite and natrojarosite in the Mine No. 6 “Exi” is therefore unique. A study of the chemical composition of these minerals and PXRD data of selected minerals are presented in this publication.
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References
Bolanz RM, Wierzbicka-Wieczorek M, Giester G, Göttlicher J, Steininger R (2016) Structural incorporation of As5+ into phosphosiderite by a strengite/scorodite–like arrangement. ChemistrySELECT 1(14): 4152-4160. https://doi.org/10.1002/slct.201600884
Brothernton PD, Maslen EN, Pryce MW, White AH (1974) Crystal structure of collinsite. Austr J Chem 27: 653-656. https://doi.org/10.1071/ch9740653
Capitelli F, Chita G, Cavallo A, Bellatreccia F, Ventura GD (2011) Crystal structure of whiteite-(CaFeMg) from Crosscut Creek, Canada. Z Krist 226: 731-738. https://doi.org/10.1524/zkri.2011.1393
Elliott P (2016) Jahnsite-(CaFeMg), a new mineral from Tom’s quarry, South Australia: description and crystal structure. Eur J Mineral 28: 991-996. https://doi.org/10.1127/ejm/2016/0028-2562
Fanfani L, Zanazzi PF (1966) La struttura cristallina della metastrengite. Atti della Accademia Nazionale dei Lincei, Classe di Scienze Fisiche, Matematiche e Naturali, Rendiconti Serie 8(40): 880-889
Grey IE, Mumme WG, Neville SM, Wilson NC, Birch WD (2010) Jahnsite - whiteite solid solutions and associated minerals in the phosphate pegmatite at Hagendorf-Süd, Bavaria, Germany. Mineral Mag 74(6): 969-978. https://doi.org/10.1180/minmag.2010.074.6.969
Ismagilova RM, Rieck B, Kampf AR, Giester G, Zhitova ES, Lengauer CL, Krivovichev SV, Zolotarev AA, Ciesielczuk J, Mihkailova JA, Belakovsky JI, Bocharov VN, Shilovskikh VV, Vlasenko NS, Nash BP, Adams PM (2022) Goldhillite, Cu5Zn(AsO4)2(OH)6·H2O, a new mineral species, and redefinition of philipsburgite, Cu5Zn[(AsO4)(PO4)](OH)6·H2O, as an As–P ordered species. Mineral Mag 86(3): 436-446. https://doi.org/10.1180/mgm.2022.36
Kampf AR, Steele IM, Loomis TA (2008) Jahnsite-(NaFeMg), a new mineral from the Tip Top mine, Custer County, South Dakota: Description and crystal structure. Amer Mineral 93: 940-945. https://doi.org/10.2138/am.2008.2771
Kampf AR, Adams PM, Nash BP (2016) Whiteite-(CaMgMg), CaMg3Al2(PO4)4(OH)2·8H2O, a new jahnsite-group mineral from the Northern Belle mine, Candelaria, Nevada, USA. Can Mineral 54: 1513-1523. https://doi.org/10.3749/canmin.1600051
Kolitsch U, Rieck B, Brandstätter F, Schreiber F, Fabritz KH, Blaß G, Gröbner J (2014) Neufunde aus dem altem Bergbau und den Schlacken von Lavrion (I). Mineralien-Welt 25(1): 60-75
Laugier J, Bochu B (2011) LMGP-suite of programs for the interpretation of X-ray experiments. Accessed in April 2011 at http://www. ccp14.ac.uk/tutorial/lmgp
Marinos G, Petrascheck WE (1956) Laurium: Geological and geophysical research. Greece. Inst Geol Subsurf Res 4: 1-246
Möckel S (2000) Strashimirit und 11 weitere Neubestimmungen aus Lavrion (GR). Lapis 25(7-8): 74
Moore PB (1974) I. Jahnsite, segelerite, and robertsite, three new transition metal phosphate species II. Redefinition of overite, an isotype of segelerite III. Isotypy of robertsite, mitridatite, and arseniosiderite. Amer Mineral 59: 48-59
Moore PB, Araki T (1974) Jahnsite, CaMn2+Mg2 (H2O)8Fe3+2(OH)2[PO4]4: A novel stereoisomerism of ligands about octahedral corner-chains. Amer Mineral 59: 964-973
Moore PB, Ito J (1978) I. Whiteite, a new species, and a proposed nomenclature for the jahnsite-whiteite complex series. II. New data on xanthoxenite. III. Salmonsite discredited. Mineral Mag 42: 309-323. https://doi.org/10.1180/minmag.1978.042.323.01
Perdikatsis B (1991) X-ray powder diffraction study of francolite by the Rietveld method. Material Science Forum 79: 809-814. https://doi.org/10.4028/www.scientific.net/msf.79-82.809
Pouchou JL, Pichoir F (1985) “PAP” (φρZ) procedure for improved quantitative microanalysis. In: Armstrong JT (Ed) Microbeam Analysis: 104-106. San Francisco Press, San Francisco
Rieck B, Kolitsch U, Voudouris P, Giester G, Tzeferis P (2018) Weitere Neufunde aus Lavrion, Griechenland. Mineralien-Welt 29(5): 32-77
Stormer JC, Pierson MJ, Tacker RC (1993) Variation of F and Cl X-ray intensity due to anisotropic diffusion of apatite during electron microprobe analysis. Amer Mineral 78: 641-648
Voudouris P, Melfos V, Mavrogonatos C, Photiades A, Moraiti E, Rieck B, Kolitsch U, Tarantola A, Scheffer C, Morin D, Vanderhaeghe O, Spry PG, Ross J, Soukis K, Vaxevanopoulos M, Pekov IV, Chukanov NV, Magganas A, Kati M, Katerinopoulos A, Zaimis S (2021) The Lavrion mines: A unique site of geological and mineralogical heritage. Minerals 11(76): 1-22. https://doi.org/10.3390/min11010076
Yakovenchuk VN, Keck E, Krivovichev SV, Pakhomovsky YA, Selivanova EA, Mikhailova JA, Chernyatieva AP, Ivanyuk GY (2012) Whiteite-(CaMnMn), CaMnMn2Al2[PO4]4(OH)2·8H2O, a new mineral from the Hagendorf-Süd granitic pegmatite, Germany. Mineral Mag 76(7): 2761-2771. https://doi.org/10.1180/minmag.2012.076.7.09
