Occurrence of Al-Fe phosphates in conglomerates at Kamenný Újezd near Rokycany (Czech Republic)
Keywords
Abstract
An interesting occurrence of secondary phosphates fluorwavellite, variscite and strengite in the Barrandian area has been newly discovered in Kamenný Újezd near Rokycany (Czech Republic). Phosphates crystallize on cracks of hornfels pebbles in weathered conglomerates and in cavities of quartz veins that penetrate them. Fluorwavellite forms white, needle-like, radially rayed aggregates with a diameter of up to 3 cm on the cracks and white to slightly yellowish spherical aggregates up to 1 cm in size in cavities. Variscite occurs in fissures in the form of flat radial aggregates of white colour and pearly lustre up to 0.8 mm in size. In the cavities of quartz veins, variscite forms spherical aggregates up to 0.8 mm in diameter and reniform layers of white, light beige, light gray, and light pink colours. Variscite is covered with a layer of strengite approximately 0.06 to 0.08 mm thick. The WDS quantitative analyses, X-ray powder patterns, and refined unit cell parameters are given for all described mineral phases.
Files
References
Ardit M, Phillips BL, Bish DL. (2022) Crystal structure determination of orthorhombic variscite2O and its derivative AlPO4 structure at high temperature. Am Mineral 107(7): 1385-1395. https://doi.org/10.2138/am-2022-8119
Breithaupt A (1840) Beraunit, ein neues Glied der Phyllit - Ordnung. J Prakt Chem 20: 66-67. https://doi.org/10.1002/prac.18400200107
Chlupáč I, Brzobohatý R, Kovanda J, Stráník (2002) Geologická minulost České republiky. 1-436, Academia, Praha
Kampf AR, Adams PM, Barwood H, Nash BP (2015) Fluorwavellite, IMA 2015-077. CNMNC Newsletter 28, 1862; Mineral Mag 79: 1859-1864
Kampf AR, Adams PM, Barwood H, Nash BP (2017) Fluorwavellite, Al3(PO4)2(OH)2F·5H2O, the fluorine analogue of wavellite. Am Mineral 102: 909-915. https://doi.org/10.2138/am-2017-5948
Laugier J, Bochu B (2011) LMGP-suite of programs for the interpretation of X-ray experiments. http://www.ccp14.ac.uk/tutorial/lmgp. přístup duben 2011
Pouchou JL, Pichoir F (1985) “PAP” (φρZ) procedure for improved quantitative microanalysis. In: Armstrong JT (ed.) Microbeam Analysis: 104-106, San Francisco Press, San Francisco
Salvador PS, Fayos J (1972) Some aspects of the structural relationship between “Messbach-type” and “Lucin-type” variscites. Am Mineral 57: 36-44
Steinmann J (1825) Vorträge d öffentl Sitz d k böhm Gesselsch d Wissensch
Taxer K, Bartl H (2004) On the dimorphy between the variscite and clinovariscite group: refined finestructural relationship of strengite and clinostrengite, Fe(PO4) ·2H2O. Crystal Res Technol 39: 1080-1088. https://doi.org/10.1002/crat.200410293
Ulrich F (1929) Variscit a barrandit z Třenic u Zbiroha. Rozpr II. Tř Čes Akad Věd a Umění 39(17): 1-13
Vrtiška L (2023a) Minerální asociace sekundárních puklinových fosfátů v závislosti na typu hostitelské horniny Českého masivu. Dizertační práce. Masarykova Univerzita, Brno. 1-109
Vrtiška L (2023b) Naleziště sekundárních puklinových fosfátů v Českém masivu a jejich členění a porovnání v závislosti na typu hostitelské horniny. Bull Mineral Petrolog 31(2): 123-166. https://doi.org/10.46861/bmp.31.123
Vrtiška L (2025) Historické naleziště fosfátů na vrchu Čilina u Rokycan. Minerál 33(5): 412-417
Vrtiška L, Malíková R, Sejkora J (2016) Zajímavý výskyt fosfátů v okolí Líštěnce u Votic (Česká republika). Bull mineral-petrolog Odd Nár Muz (Praha) 24(1): 114-131
Vrtiška L, Sejkora J, Malíková R (2019) Studium sekundárních fosfátů s allanpringitem a tvrdýitem z opuštěného ložiska železných rud Krušná hora u Berouna (Česká republika). Bull Mineral Petrolog 27(2): 231-246
Vrtiška L, Zemek V, Malíková R (2020) Vzácný allanpringit - produkt alterace fluorwavellitu z lomu Milina u Zaječova (Česká republika). Bull Mineral Petrolog 28(1): 126-131. https://doi.org/10.46861/bmp.28.12
